Heat oven to 425°F. Toss zucchini with oil and 1/4 teaspoon salt on a sheet pan and roast for 20 to 25 minutes, turning once, until browned and fairly dry.
Meanwhile, brown sausage in a skillet over medium heat for 8 to 10 minutes, breaking it finely, until 160°F. Drain excess fat, add garlic for 1 minute, then stir in tomatoes, water, oregano, pepper and remaining salt and simmer for 8 minutes.
Butter a 6-quart slow cooker and spread 3/4 cup sausage sauce over the bottom. Layer half the uncooked refrigerated ravioli, half the zucchini, half the remaining sauce and half the mozzarella.
Repeat the layers with the remaining ravioli, zucchini, sauce and cheese, covering all exposed pasta edges. Cover and cook on low for 2 to 2 1/2 hours, checking after 90 minutes, until the ravioli centers are tender and the filling reaches 165°F.
Switch off, uncover and rest for 10 minutes. Fold the chopped basil lightly into the top sauce and divide into six portions with a wide spoon, keeping the filled pasta pieces whole.